Palazzo Chigi in Ariccia Comune di Ariccia
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The archival material pertaining tothe real estate interests of the family is plentiful, going back to nearly the entire 19th and 20th centuries. Of particular interest is the correspondence between the Granduke Nicholas Mikailovic Romanov and Princess Leonilla Bariatinsky, mother of Antonietta Chigi, during the Russian revolution.
 
The library collection is divided into two sections: the 17th century section, the so-called "Library of the campaign of Prince Augustin Chigi", composed mostly of theatrical booklets of the 17th century, the other 19th-20th century section, that documents the various cultural and scientific interests of the family. Very important librarians have added to the collection, like Redig De Campos, once director of the Vatican Museums, or the librarian Beatrice Canestro Chiovenda, art historian.